Excellence Initiative - Research University
ul. Gagarina 7, 87-100 Toruń
tel.: +48 56 611-43-02
fax: +48 56 611-45-26
e-mail: wydzial@chem.umk.pl

Kinetics and Mechanisms of Chemical Processes of Coordination Compounds in Solution


RESEARCH PROFILE

The research team focuses on mechanistic studies in inorganic and bioinorganic chemistry, especially in terms of the activation of small molecules such as NO, HNO, NAD+/NADH, and H2O2. Fast kinetic and rapid-scan techniques are employed to elucidate the nature of the underlying activation process, which in many cases are transition metal complexes. More recently, the group has developed an interest in the synthesis of mixed-valent metal ion-pair complexes with unexpected magnetic properties.


GROUP MEMBERS

Prof. dr hab. Rudi van Eldik
dr hab. Anna Katafias, prof. UMK, email: katafias@umk.pl
dr Olga Impert
mgr Marta Chrzanowska
mgr Aniela Trocha


PROJECTS, GRANTS

Prof. Rudi van Eldik – NCN grant OPUS 19 “Mechanistic clarification of the interaction of nanoparticles and nanoscale coordination compounds at the interface of multiphase chemical and medicinal related processes”.


SELECTED PUBLICATIONS

D. Chatterjee, M. Chrzanowska, A. Katafias, R. van Eldik, Reaction mechanisms relevant to the formation and utilization of [Ru(edta)(NO)] complexes in aqueous media, J. Inorg. Biochem., 225, 111595 (2021).

A. Trocha, O. Impert, A. Katafias and R. van Eldik, Mechanistic details of the catalytic degradation of methylene blue by hydrogen peroxide in basic solution. The unexpected innocence of percarbonate, Polyhedron, 210, 115507 (2021).

M. Oszajca, G. Drabik, M. Radoń, A. Franke, R. van Eldik and G. Stochel, Experimental and computational insight into the mechanism of NO binding to ferric microperoxidase. The likely role of tautomerization to account for the pH dependence, Inorg. Chem. Forum on Renaissance in NO Chemistry, in press (2021).This manuscript is featured on the cover of the xth issue of Inorg. Chem.

D. Chatterjee, M. Oszajca, A. Katafias, R. van Eldik, Electrochemistry of Ru(edta) complexes relevant to small molecule transformations: Catalytic implications and challenges, Coord. Chem. Rev., 436, 213773 (2021).

J. Polaczek, H. Subedi, Ł. Orzeł, L. Lisboa, R.B. Cink, G. Stochel, N.E. Brasch and R. van Eldik, Mechanistic studies on the reaction between aquacobalamin and the HNO donor Piloty’s acid over a wide pH range in aqueous solution, Inorg. Chem., 60, 2964−2975 (2021). This manuscript is featured on the cover of the 5th issue of Inorg. Chem.

M. Chrzanowska, A. Katafias, R. van Eldik, Can a non-organometallic ruthenium(II) polypyridyl amine complex catalyze hydride transfer? Mechanistic insight from solution kinetics on the reduction of coenzyme NAD+ by formate, Inorg. Chem., 59, 14944-14953 (2020).

O. Impert, A. Kozakiewicz, G. Wrzeszcz, A. Katafias, A. Bieńko, R. van Eldik, A. Ozarowski, Characterization of the mixed-valence Ru(II)/Ru(III) ion-pair complex. Unexpected HF-EPR evidence for Ru(III)-Ru(III) dimer coupling, Inorg. Chem., 59, 8609−8619 (2020).

C.D. Hubbard, D. Chatterjee, M. Oszajca, J. Polaczek, O. Impert, M. Chrzanowska, A. Katafias, R. Puchta, R. van Eldik, Inorganic Reaction Mechanisms. A Personal Journey, Dalton Trans., 49, 4599-4659 (2020). Perspective Article for the 50th Anniversary of the RSC IRMDG for Dalton Transactions; This manuscript is featured on the cover of the 15th issue of Dalton Trans.!

M. Chrzanowska, A. Katafias, O. Impert, A. Kozakiewicz, A. Surdykowski, P. Brzozowska, A. Franke, A. Zahl, R. Puchta, R. van Eldik, Structure and reactivity of [RuII(terpy)(N^N)Cl]Cl complexes: consequences for biological applications, Dalton Trans., 46, 10264 – 10280 (2017).